Assalam-o-alaikum!
Shear reinforcement values indicated on the column member are generally the maximum values for the two shear axes, whether these are from on load combo or from two different load combos. Right-cIick on the member reinforcement diagram generally leads straight to load combo resulting in the maximum longitudinal or maximum shear reinforcement. However, as you have indicated, I am unsure, why this does not always happen. Surely, someone else might be able to explain this.
Interpretation of shear reinforcement value 'Av/s', given by ETABS, is not very difficult.
Since your units are 'kip-in", Av (i.e. cross-sectional area of ties) is in 'sq.in.' and s (i.e., spacing) in 'inches'.
For your case, Av/s = 0.045.
For 2-legged #3 ties, Av = 0.11x 2 = 0.22 sq. in.
Substitution of value of Av in above equation, results in required tie spacing, s = 0.22 / 0.045 = 4.88 in.
Regards.